2.3.1 — Evaporation vs. Boiling
Both evaporation and boiling convert liquid water into vapour, but they are fundamentally different processes. Confusing them leads to mistakes when diagnosing why moisture leaves a surface or why a refrigerant behaves the way it does at a given pressure.
Evaporation
Occurs only at the surface of a liquid, at any temperature above freezing. High-energy molecules near the surface escape into the air as vapour.
- Slow and continuous process
- No bubbles form in the liquid
- Can occur well below the boiling point
- Cools the remaining liquid (evaporative cooling)
- Rate increases with temperature, airflow, and surface area
Boiling
Occurs throughout the entire volume of the liquid, only when the liquid reaches its boiling point at the current pressure.
- Rapid and vigorous process
- Vapour bubbles form and rise through the liquid
- Requires continuous heat input to sustain
- Temperature stays constant during boiling
- Boiling point changes with pressure
Example — Evaporative Cooling in Everyday Life
When you step out of a swimming pool on a warm day, your skin feels cold even though the air temperature may be 90°F. The water is evaporating from your skin — not boiling. As each water molecule escapes, it carries away latent heat (970 BTU/lb), cooling the surface it leaves behind.
- Sweat evaporation — the body’s natural cooling system works on exactly this principle.
- Wet coil surfaces — condensate on an evaporator coil can re-evaporate if airflow over it slows down, reducing moisture removal efficiency.
- Wet-bulb temperature — measured by a thermometer with a wet wick; evaporation cools it below the dry-bulb (air) temperature. The difference indicates humidity level.